Showing 1 - 6 of 6 Items
Developing methods of transient absorption spectroscopy for the study of triplet state photoacids Access to this record is restricted to members of the Bowdoin community. Log in here to view.
Date: 2023-01-01
Creator: Jack R Callahan
Access: Access restricted to the Bowdoin Community
Phenylisocyanide Ligand Synthesis and Coordination to a Cobalt Catalyst for Dimerization of Linear Alpha Olefins Access to this record is restricted to members of the Bowdoin community. Log in here to view.
Date: 2020-01-01
Creator: Julia Hazlitt Morris
Access: Access restricted to the Bowdoin Community
Characterizing the exhumation path of the first ultrahigh-pressure terrane in North America Access to this record is restricted to members of the Bowdoin community. Log in here to view.
Date: 2015-05-01
Creator: Zachary FM Burton
Access: Access restricted to the Bowdoin Community
Discovery and characterization of novel crustin family antimicrobial peptides (AMPs) in the American lobster, Homarus americanus, using transcriptomics and peptidomics Access to this record is restricted to members of the Bowdoin community. Log in here to view.
- Restriction End Date: 2027-06-01
Date: 2022-01-01
Creator: Emily Yuan-ann Pan
Access: Access restricted to the Bowdoin Community
The Photocatalytic Degradation of Ibuprofen and Atenolol Using Bismuth Oxychloride and Titanium Dioxide
Date: 2021-01-01
Creator: Kamyron Anthony Speller
Access: Open access
- Pharmaceuticals and personal care products (PPCPs) are contaminating natural bodies of water and are problematic for aquatic organisms and ecosystems. Generally, PPCPs are introduced to water systems due to incomplete removal by wastewater treatment plants (WWTPs). As such, it is vital to find ways to remediate these problematic contaminants before they are discharged into the environment. In this study, two photocatalysts¾titanium dioxide (TiO2) and bismuth oxychloride (BiOCl)¾were compared to determine their relative efficiencies (degradation rates) and dominant degradation mechanism (hydroxyl radical production or direct oxidation) with the goal of photocatalytically degrading two pharmaceuticals, atenolol and ibuprofen, using UV (254 nm) light. While TiO2 has been used extensively for photocatalytic degradation, BiOCl is a newer photocatalyst. The two pharmaceuticals selected for study represent two large classes of drugs (aryloxypropanolamine and propionic acid derivatives, respectively) that have been detected in the influent into and effluent from wastewater treatment plants and in the environment. When irradiated at 254 nm, BiOCl degrades ibuprofen with a rate constant 15 times greater than TiO2. On the other hand, TiO2 degrades atenolol with a rate constant 2.2 times greater than BiOCl. LCMS analysis of photodegradation products reveals different products produced by the two photocatalysts, providing evidence for the dominance of different degradation mechanisms for the two photocatalysts. In summary, this work suggests that BiOCl, potentially used in combination with TiO2, holds potential for degrading PPCPs in natural bodies of water.
Development of a Schiff base Synthetic Platform for 8-phenyliminonaphthol Photoacids Access to this record is restricted to members of the Bowdoin community. Log in here to view.
Date: 2023-01-01
Creator: Ibrahim G. Saleh
Access: Access restricted to the Bowdoin Community