Showing 1 - 8 of 8 Items
Activation of Hydrogen by Sterically Modulated Coinage Metal Catalysts via Mutual Quenching of Hard/Soft Acid/Base Mismatches
Date: 2024-01-01
Creator: Zach Leibowitz
Access: Open access
- To mitigate the devastating environmental impacts of climate change in the coming decades, it is imperative that we replace the use of fossil fuels with renewable energy sources such as wind, solar, and hydroelectric. As these renewable energy sources are inherently intermittent, there exists a need for sustainable mechanisms to store renewable energy for later use. While the direct use of dihydrogen (H2) as a combustible fuel would allow for energy storage without the harmful release of carbon dioxide (CO2) upon combustion, the practicality of H2 as a synthetic fuel is limited by its low volumetric energy density. Combining sustainable H2 production (e.g. electrolysis using energy from renewable sources) with subsequent carbon fixation (e.g. the hydrogenation of CO2) represents a promising pathway to the sustainable production of high-density synthetic fuels. We hypothesize that such a process could be catalyzed by an IPr**-supported catalyst containing a hard/soft acid/base (HSAB) mismatch, with a polarizable coinage metal acting as a soft acid. As such, the aim of our project is the construction of a catalogue of IPr**-supported copper, silver, and gold catalysts that we anticipate will facilitate the heterolysis of dihydrogen and subsequent hydrogenation of CO2. In the present paper, we report the synthesis and characterization of an IPr**-silver complex which will serve as a precursor to many of our proposed HSAB mismatch catalysts and discuss next steps as we construct our catalogue of catalysts.
Structural and methodological factors influencing the sorption of alkylpyridiniums to aluminosilicates Access to this record is restricted to members of the Bowdoin community. Log in here to view.
Date: 2023-01-01
Creator: Seamus Frey
Access: Access restricted to the Bowdoin Community
Sorption of Cationic Heterocyclic Amines to Soils: Effects of Charge Delocalization and other Factors Access to this record is restricted to members of the Bowdoin community. Log in here to view.
Date: 2023-01-01
Creator: Mariah McKenzie
Access: Access restricted to the Bowdoin Community
Synthesis and Metalation of a Bifunctional Ligand for Hydrogen Activation This record is embargoed.
- Embargo End Date: 2028-05-18
Date: 2023-01-01
Creator: Eliana Roberts
Access: Embargoed
The Photocatalytic Degradation of Ibuprofen and Three Beta-Blockers using BiOCl: An Investigation into the Mechanisms Responsible for Photocatalytic Activity Access to this record is restricted to members of the Bowdoin community. Log in here to view.
- Restriction End Date: 2027-06-01
Date: 2022-01-01
Creator: Jeffrey Charles Price
Access: Access restricted to the Bowdoin Community
Evaluation of the Effectiveness of Probe Compounds at Predicting Anionic Pharmaceutical Sorption to Soils Access to this record is restricted to members of the Bowdoin community. Log in here to view.
Date: 2021-01-01
Creator: Ben Cook
Access: Access restricted to the Bowdoin Community
The Determination of the Aqueous Oxidation Potentials of Aniline and Sixteen of its Derivatives via Ultrafast Cyclic Voltammetry to Model the Photocatalyzed Degradation of Organic Pollutants in Natural Bodies of Water Access to this record is restricted to members of the Bowdoin community. Log in here to view.
Date: 2014-05-01
Creator: Joshua V Pondick
Access: Access restricted to the Bowdoin Community
The Photodegradation of Endocrine Disrupting Compounds in Aqueous Solutions Access to this record is restricted to members of the Bowdoin community. Log in here to view.
Date: 2014-05-01
Creator: Peyton C Morss
Access: Access restricted to the Bowdoin Community